Spinel ferrites MFe2O4 (M = Co, Cu, Zn) for photocatalysis: theoretical and experimental insights

Hall, C. A., Ferrer, P., Grinter, D. C., Kumar, S., da Silva, I., Rubio-Zuazo, J., Bencok, P., de Groot, F., Held, G. and Grau-Crespo, R. ORCID: https://orcid.org/0000-0001-8845-1719 (2024) Spinel ferrites MFe2O4 (M = Co, Cu, Zn) for photocatalysis: theoretical and experimental insights. Journal of Materials Chemistry, 12 (43). pp. 29645-29656. ISSN 0959-9428 doi: 10.1039/D4TA04941A

Abstract/Summary

Spinel ferrites exhibit significant promise in photocatalysis and other applications due to their compositional diversity and favourable electronic structure, magnetism, and partially tuneable cation distribution. However, their complex properties, for example, the different behaviour of bulk and nanostructured materials, are not well understood. Here, we combine advanced computational and experimental methods with reactivity measurements to explore the inversion degrees, electronic structures, and photocatalytic activities of MFe2O4 spinels (M = Co, Cu, Zn). X-ray diffraction and anomalous X-ray scattering measurements determined bulk inversion degrees of 0.81, 0.91, and 0.26 for CoFe2O4, CuFe2O4, and ZnFe2O4, respectively. Photocatalytic tests showed that only ZnFe2O4 is active in the oxygen evolution reaction (OER), which correlates with its favourable band alignment, as determined through electronic structure simulations. Surface-sensitive X-ray Absorption Spectroscopy (XAS) measurements provided insights into the cation distributions at the surfaces, showing significant deviations from bulk properties, particularly in ZnFe2O4 in which 52% of the near-surface tetrahedral sites are occupied by Fe cations, compared to 26% in the bulk. DFT simulations of ZnFe2O4 illustrated how the surface terminations can alter the thermodynamic preference for cation distribution in comparison with the bulk. Our findings illustrate the complex interplay between surface and bulk properties in spinel ferrites.